Silcretes (silica-rich duricrusts) form through the mobilization, transport, and re-precipitation of silica within near-surface soil/regolith profiles, a process favored by arid to semi-arid climatic conditions with poor drainage (allowing prolonged residence time and evaporative concentration of silica-bearing groundwater) and elevated (alkaline) groundwater pH, which increases the solubility and mobility of silica prior to its precipitation as the environment becomes locally more concentrated or pH shifts.
Silica has notably higher solubility in alkaline (high pH) waters compared to near-neutral or acidic waters, so silcrete formation is favored where groundwater pH is...
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